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Q.

Which transition in Li2+ would have the same wavelength as the 2 → 4 transition in He+  ion?

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a

4 → 2

b

2 → 4

c

3 → 6

d

6 → 2

answer is C.

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Detailed Solution

ν¯=1λ=RZ21n12-1n22  ν ¯2→4He+ =1λ = R(2)214-116=34R= ν ¯x→yLi+2 (If λ is same then ν is also same)  3R4=R(3)21x2-1y2  from options , x=3 , y=6
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Which transition in Li2+ would have the same wavelength as the 2 → 4 transition in He+  ion?