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Q.

White phosphorus on reaction with concentrated NaOH solution in an inert atmosphere of CO2 gives phosphine and compound (X). (X) on acidification with HCl gives compound (Y).  among the reaction the compound which will give garlic smell is

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a

Phosphine

b

Carbon di oxide

c

Sodium phosphate

d

White phosphorous

answer is A.

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Detailed Solution

P4+3NaOH+3H2O→3NaH2PO2+PH3In this reaction phosphine has garlic smell (PH3)
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