Q.
The work done when 65.38g of zinc dissolved completely in HCl in an open beaker at 300k is
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a
– 2494.2J
b
– 249.4J
c
1J
d
– 24.94J
answer is A.
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Detailed Solution
Zn + 2HCl → ZnCl2+H2 ↑No. of moles of Zn = No. of mole of H2 liberated=65.3865.38=1 mole VH2=nRTP=1×0.0821×3001 atm =24.63 lit w = - PΔV = - 1 atm [24.63-0] = -24.63 x 101.3 J = - 2495J
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