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Q.

x mol N2O4  is taken at P1  atm in a closed vessel & heated. When 75% N2O4  dissociated at equilibrium, total pressure is found to be P2  atm. The relation between P1&P2  is

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a

P1:P2=7:4

b

P1:P2=7:2

c

P1:P2=4:7

d

P1:P2=3:4

answer is C.

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Detailed Solution

N2O4⇌2NO2     x                 0      0.75x           1.5x_ 0.25x           1.5x Given   x moles           P1          1.75x moles        P2          P1P2=n1n2=x1.75x=47
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x mol N2O4  is taken at P1  atm in a closed vessel & heated. When 75% N2O4  dissociated at equilibrium, total pressure is found to be P2  atm. The relation between P1&P2  is