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Q.

Yellow coloured Werner’s cobalt complex gives 3 moles of white coloured AgCl precipitate with AgNO3 solution. The formula of the complex is

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a

CoCl3 . 3NH3

b

CoCl3 . 5NH3

c

CoCl3 . 4NH3

d

CoCl3 . 6NH3

answer is D.

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Detailed Solution

One mole of yellow coloured Co (III) complex which contains three ionizable chloride ions is CoCl3 . 6NH3 (or) [Co(NH3)6]Cl3 .CoNH36Cl3⇌CoNH36+3+3Cl−
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