Zinc can be coated on iron to produce galvanized iron but the reverse is not possible. It is because
zinc is lighter than iron
zinc has lower melting point than iron
zinc has lower negative electrode potential than iron
zinc has higher negative electrode potential than iron
Reduction potential values of
EZn2+/Zn°=-0.76 V and EFe2+/Fe°=-0.44 V
Thus, due to higher negative electrode potential value of zinc than iron, iron cannot be coated on zinc.