Q.
The zinc/silver oxide cell is used in electric watches. The reaction is as following,Zn2++2e-→Zn;E°=-0.760 VAg2O+H2O+2e-→2Ag+2OH-;E°=0.344 V If F is 96,500Cmol-1,ΔG° of the cell will be
see full answer
Talk to JEE/NEET 2025 Toppers - Learn What Actually Works!
Real Strategies. Real People. Real Success Stories - Just 1 call away
An Intiative by Sri Chaitanya
answer is 2.
(Unlock A.I Detailed Solution for FREE)
Ready to Test Your Skills?
Check your Performance Today with our Free Mock Test used by Toppers!
Take Free Test
Detailed Solution
ΔG0 = −nFE0From the reaction, n = 2ΔG0 = −296500 Ecello .........(1)Ecello = Ecathodeo − EanodeoZn+2 + 2e− → Zn, E0=−0.76VAg2O+H2O+2e¯ → 2Ag+2OH−, E0=+0.344VSRP value of Ag2O half cell is high ∴ it acts like cathodeThus … Anode ; Zn→Zn+2 +2e-; Cathode; Ag2O +H2O +2e-→ 2Ag +2OH-Zn +Ag2O+H2O → Zn+2 + 2Ag + 2OH− Ecello = +0.344−−0.76= + 1.104 VSubstituting the value in ---(1)ΔG0 = −296.5 1.104kJ= –213.072 kJ
Watch 3-min video & get full concept clarity