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Calculate the ratio of the mean free paths of the molecules of two gases having molecular diameters 1 Ao and 2 Ao. The gases may be considered under identical conditions of temperature, pressure and volume.

a
2:1
b
3:1
c
4:3
d
4:1

detailed solution

Correct option is D

Mean free path of a molecule is given by   l=12d2nwhere n = number of molecules/volume           d = diameter of the moleculeNow, we can write l∝1d2 Given, d1=1Å,d2=2A As  l1∝1d12 and l2∝1d22⇒ So, l1l2=d2d12=212=41 Hence, l1:l2=4:1

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The mean free path of the molecules of two gases having molecular diameters  1Ao  and 2Ao is N: 1. Gases are under identical conditions of temperature, pressure  and volume. Find N.


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