A calorimeter of water equivalent 20 g contains 180g of water at ${25}^0$C. ‘m’ grams of steam at ${100}^0$C is mixed in it till the temperature of the mixture is ${31}^0$C. The value of ‘m’ is close to (Latent heat of water = 540 cal $g^{-1}$, specific heat of water = 1 cal $g^{-1}$  ${ }^0{C}^{-1}$)

A calorimeter of water equivalent 10 g contains a liquid of mass 50 g at 40^oC. When m gram of ice at -10^oC is put into the calorimeter and the mixture is allowed to attain equilibrium, the final temperature was found to be 20^oC. It is known that specific heat capacity of the liquid changes with temperature as $\mathrm{S}=\left(1+\frac{\mathrm{\theta }}{500}\right)\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$where $\mathrm{\theta }$ is temperature in ^oC. The specific heat capacity of ice, water and the calorimeter remains constant and values are ${\mathrm{S}}_{\text{ice }}=0.5\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$; ${\mathrm{S}}_{\text{water }}=1.0\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$ and latent heat of fusion of ice is ${\mathrm{L}}_{\mathrm{f}}=80{\mathrm{calg}}^{-1}$. Assume no heat loss to the surrounding and calculate the value of m in grams.