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Q.

The capacity of a vessel is 3 L. It contains 6 g oxygen, 8g nitrogen and 5 g CO2 mixture at 27oC. If R = 8.31 J/mol K, then the pressure in the vessel in N/m2 will be (approx.)

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a

5×105

b

5×104

c

106

d

105

answer is A.

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Detailed Solution

By Dalton's lawP=P1+P2+P3=μ1RTV+μ2RTV+μ3RTV=RTVμ1+μ2+μ3=RTVm1M1+m2M2+m3M3=8.31×3003×10-3632+828+544=498×103=500×103=5×105N/m2
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