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Q.

In a closed container of volume 10-3 m3, O2 gas is filled at temperature 400 K and pressure 1.5 atm. A small hole is made in the container from which gas leaks out to open atmosphere. After sometime the temperature and pressure of container become equal to that of surrounding. The mass of gas (in grams) that leaks out from the container is ___________. (Atmospheric temperature = 300 K)

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answer is 0.16.

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Detailed Solution

If initially there is m1 mass of O2 gas in the container, from gas law we have P1V=m132RTor   m1=32PVRT=32×1.5×105×10−38.314×400=1.443gFinally if m2 mass of O2 is left in the container, from gas lawWe have P2V=m232RTor  m2=32 P2VRT=32×1.5×105×10−38.314×300=1.283gThus mass of gas leaked out, Δm=m1−m2=1.443−1.283=0.16g
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