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Heat ;work and internal energy

Question

A closed vessel contains 0.1 mole of a monatomic ideal gas at 200 K. If 0.05 mole of the same gas at 400 K is added to it, the final equilibrium temperature (in K) of the gas in the vessel will be close to ___________ .

Moderate
Solution

Assuming  Q=0,  W=0
We have      ΔU=0 

           n1CV1TfT1+n2CV2TfT2=0

   n1CV1TfT1=-n2CV2TfT2=0

   n1TfT1=-n2TfT2For same gasCV1=CV2 

   n1Tf-  n1T1=-n2Tf+n2T2

   n1Tf+n2Tf=  n1T1+n2T2

    Tf=n1T1+n2T2n1+n2        =0.1200+0.054000.1+0.05

=20+200.15          =266.6666 K



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