Q.
A closed vessel contains 0.1 mole of a monatomic ideal gas at 200 K. If 0.05 mole of the same gas at 400 K is added to it, the final equilibrium temperature (in K) of the gas in the vessel will be close to ___________ .
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answer is 0266.67.
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Detailed Solution
Assuming Q=0, W=0We have Δ U=0 ⇒ n1CV1Tf−T1+n2CV2Tf−T2=0⇒ n1CV1Tf−T1=-n2CV2Tf−T2=0⇒ n1Tf−T1=-n2Tf−T2∵For same gasCV1=CV2 ⇒ n1Tf- n1T1=-n2Tf+n2T2⇒ n1Tf+n2Tf= n1T1+n2T2⇒ Tf=n1T1+n2T2n1+n2 =0.1200+0.054000.1+0.05=20+200.15 =266.6666 K
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