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Q.

A container of fixed volume has mixture of one mole of hydrogen and one mole of helium in equilibrium at temperature T. Assuming the gases are ideal, the correct statement(s) is (are)

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a

The average energy per mole of the gas mixture is 2RT.

b

The ratio of speed of sound in the gas mixture to that in helium has is  6/5.

c

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2.

d

The ratio of the rms speed of helium atoms to that of hydrogen molecules is 1/2

answer is A.

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Detailed Solution

(A) Total internal energy  U=f12nRT+f22nRT Uaveper mole=U2n=145RT+3RT=2RT(B)  γmix=n1CP1+n2CP2n2CV1+n2CV2=17R2+15R215R2+13R2=32Mmix=n1M1+n2M2n1+n2=M1+M22=2+42=3Speed of sound  V=γRTM⇒V∝γMVmixVHe=γmixγHe×MHeMMix=3/25/3×43=65 (D)  Vrms=3RTM⇒Vrms∝1M,  VHeVH=MHMHe=24=12
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