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Thermodynamic processes

Question

An engine takes in 5 moles of air at 20ºC and 1atm, and compresses it adiabatically to 1/10th  of the original volume. Assuming air to be a diatomic ideal gas made up of rigid molecules, the change in its internal energy during this process comes out to be X kJ. The value of X to the nearest integer is________

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Solution

Tin=10°C=10+273=293K

PVγ=constant,γ=75

TVγ-1=cont TV75-1=cont

TV7-55=cont TV25=cont

TfinV102/5=TinV2/5

Tfin=293102/5Tin=10°C=10+273=293K

ΔU=nRΔTγ1=5R2/5×293102/51=25R2102/51×293=25R22.5111×293=12.5R(1.511)×293=46 kJ



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