Q.

Initially a gas of diatomic molecules is contained in a cylinder of volume  V1 at a pressure P1 and temperature 250 K. Assuming that 25% of the molecules get dissociated causing a change in number of moles. The pressure of the resulting gas at temperature 2000 K, when contained in a volume 2V1 is given by  P2. The ratio P2/P1  is ……

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answer is 0005.00.

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Detailed Solution

Applying PV =  nRTP1V1=nR250New moles = (75% of n )+ (2)(25% of n)=1.25nSo, P22V1=1.25  nR2000∴Ratio =P2P1=5
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