Let λα,λβ and λα' denote the wavelengths of the X-rays of the Kα,Kβ and Lα lines in the characteristic X-rays for a metal
λα>λα'>λβ
λα'>λβ>λα
1λβ=1λα+1λα'
1λα+1λβ=1λα'
According to the energy diagram of X-ray spectra
∴ΔE=hcλ⇒λ∝1ΔE