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The mass, specific heat capacity and the temperature of a solid are 1000 g12  cal g.C  -1 and 80°C respectively. The mass of the liquid and the calorimeter are 900 g and 200 g. Initially, both are at room temperature 20°C. Both calorimeter and the solid are made of same material. In the steady state, temperature of mixture is 40°C, then find the specific heat capacity of the unknown liquid.

a
10 cal/g·C  ∘
b
100 cal/g·C  ∘
c
1 cal/g·C  ∘
d
0.1 cal/g·C  ∘

detailed solution

Correct option is C

m1=mass of solid=1000 gS1=specific heat of solid=12cal/g-C  ∘=S2 or specific heat of calorimeterm2= mass of calorimeter =200 gm3= mass of unknown liquid = 900 gS3= specific heat of unknown liquidFrom law of heat exchange,Heat given by solid = Heat taken by calorimeter + Heat taken by unknown liquidm1S1Δθ1=m2S2Δθ2+m3S3Δθ31000×12×(80-40)=200×12(40-20)+900×S3(40-20)Solving this equation we get, S3=1cal/g·C  ∘

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In electrical calorimeter experiment, voltage across the heater is 100.0 V and current is 10.0 A. Heater is switched on for t=700.0 s. Room temperature is θ0=10.0°C and final temperature of calorimeter and unknown liquid is θf=73.0°C. Mass of empty calorimeter is m1=1.0 kg and combined mass of calorimeter and unknown liquid is m2=3.0 kg. Find the specific heat capacity of the unknown liquid in proper significant figures. Specific heat of calorimeter = 3.0×103 J/kg°C


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