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Internal energy

Question

Nitrogen of mass 15 g is enclosed in a vessel at temperature 300 K so that it does  not lose any energy to external system. The amount of heat required to double  the root mean square velocity of these molecules is N times 2000 J. Find N.   (Round off answer to nearest multiple of 10).

Difficult
Solution

Using Law of equipartition of energy,
Energy of a gas at temperature T is U=fnRT2.
Since, Nitrogen is diatomic, f = 5. Here, n=1528 
Also,  vRMS=3kTmαT
If vRMS doubles,  T becomes 4 times.
So,  U1=55288.33002
U2=55288.312002 
So,  ΔU=U2U1=515288.312003002=10004.5J10000J=5×2000J
 



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