Steam at 100^oc is passed into 1.1 g of water contained in a calorimeter of water equivalent 0.02 g at 15^oC till the temperature of the calorimeter and its contents rises to 80^oC. The mass of the steam condensed in g is

A calorimeter of water equivalent 10 g contains a liquid of mass 50 g at 40^oC. When m gram of ice at -10^oC is put into the calorimeter and the mixture is allowed to attain equilibrium, the final temperature was found to be 20^oC. It is known that specific heat capacity of the liquid changes with temperature as $\mathrm{S}=\left(1+\frac{\mathrm{\theta }}{500}\right)\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$where $\mathrm{\theta }$ is temperature in ^oC. The specific heat capacity of ice, water and the calorimeter remains constant and values are ${\mathrm{S}}_{\text{ice }}=0.5\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$; ${\mathrm{S}}_{\text{water }}=1.0\text{ cal }{{\mathrm{g}}^{-1}}^{\circ }{\mathrm{C}}^{-1}$ and latent heat of fusion of ice is ${\mathrm{L}}_{\mathrm{f}}=80{\mathrm{calg}}^{-1}$. Assume no heat loss to the surrounding and calculate the value of m in grams.