Q.

Anhydrous <math xmlns="http://www.w3.org/1998/Math/MathML"><msub><mi>AlCl</mi><mn>3</mn></msub><mspace linebreak="newline"/></math>is covalent however when it is dissolved in water hydrated ionic species are formed. This transformation is owing to:


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a

Low hydration energy of<math xmlns="http://www.w3.org/1998/Math/MathML"><msup><mi>Al</mi><mrow><mn>3</mn><mo>+</mo></mrow></msup></math>

b

The trivalent state of Al

c

The large hydration energy of<math xmlns="http://www.w3.org/1998/Math/MathML"><msup><mi>Al</mi><mrow><mn>3</mn><mo>+</mo></mrow></msup></math>

d

The polar nature of water 

answer is B.

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Detailed Solution

Concept- Chemical compounds are generally of two types: covalent compounds and ionic compounds. Ions with the opposite charge form ionic compounds, usually as a result of the reaction of a metal with a nonmetal. In covalent compounds, the elements form the compound by sharing electrons, resulting in an electrically neutral molecule.
In solution, when AlCl3dissolves in water, dissociation occurs and AlCl3 dissociates into Al+3 and Cl-. Now, Hydration of  Al+3 and Cl-ions occur due to the large hydration energy of Al+3 ions as it dissolves in water.
Anhydrous AlCl3 is covalent, but when dissolved in water, hydrated ionic species are formed. This transformation is due to the large hydration energy of Al+3 .
Thus, in liquid or gas phase AlCl3 exists as a covalent compound, or as in the form of dimers.
But, when we dissolve AlCl3 in water, it liberates the ions of aluminium ( Al+3)and chloride ion (Cl-).
Hence, the correct answer is 2.
 
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