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Q.

For a fairly concentrated solution of a weak electrolyte AxBy, the degree of dissociation is given as

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a

α=Keqc/xy

b

α=Keq/cx+y1xxyy1/(x+y)

c

α=Keqxy/c

d

α=Keq/c(x+y)

answer is B.

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Detailed Solution

AxByxAy++yBxc(1α) c(xα) c(yα)Keq=(cxα)x(cyα)yc(1α)cx+y1xxyyαx+y

or α=Keqcx+y1xxyy1/(x+y)

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