Q.

For a particular reversible reaction at temperature T,ΔH and ΔS were found to be both positive. If Te is the temperature at equilibrium, the reaction would be spontaneous when 

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a

T>Te

b

Te is 5 times T

c

T=Te

d

Te>T

answer is C.

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Detailed Solution

Since ΔG=ΔHTΔG, we have

Reactions at equilibrium:                               ΔG=ΔHTeΔS=0

For a reaction to be spontaneous:              ΔG=ΔHTΔS<0

ΔG will be negative provided     T>Te as both ΔH and ΔS are positive.                                            

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For a particular reversible reaction at temperature T,ΔH and ΔS were found to be both positive. If Te is the temperature at equilibrium, the reaction would be spontaneous when