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Q.

For a reaction A(g) → products,           the following data are available.

Initial pressure of A, pA/ Torr    429              273                150

 Half-life period, t1/2/s               350            550                   1001

The rate of reaction at initial pressure of 500 Torr of A is

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a

5.656 Torr s−1

b

2.665 Torr s−1

c

1.665 Torr s−1

d

9.25 Torr s−1

answer is A.

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Detailed Solution

The rate ofreaction at 500 Torr is

r=kpA02=6.66×10−6 Torr −1s−1500 Torr 2=1.665 Torr −1

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