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For a reaction, 2 A(g)+3 B(g)4C(g)+D(g);  KC=322×227. If 4 moles of A are mixed with 6 moles of B in 2 liter container ; then identify the correct options.

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a
At equilibrium, [C][B]=83
b
At equilibrium, [D][A]=1
c
[A]  [B] will be negligible as compared to [C]  [D] at equilibrium. 
d
KP KC will be same for the above reaction.

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detailed solution

Correct option is A

                           2 A(g)t  =0            2-2xteq=               2(1-x) +3 B(g)2M 3-3x 3(1-x)4C(g)3m4x 4x+D(g) xx KCo=322×227 (4x)4x22(1-x)2·33(1-x)3=322×227 x1-x5=32 x1-x=2 x=2-2x x=23 [A]=2(1-x)=23 [ B]=3(1-x)=3(1-x)=1 [C]=4x=4×23=83

[D]=x=23

[C][D]=83  ;  [D][A]=2/32/3=1

As   Δng=0

  KP=KC

 

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