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Q.

For the non-stoichiometric reaction 2A+BC+D, the following kinetic data were obtained in three separate experiments, all at 298 K. 

Initial concentration of AInitial concentration of B

Initial rate of formation of 

C in mol L1s1

0.1 M0.1 M1.2×103

 

0.1 M0.2M1.2×103
0.2M0.1 M2.4×103

The rate law for the formation of C is 

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a

d[C]/dt=k[A][B]

b

d[C]/dt=k[A]

c

d[C]/dt=k[A]2[B]

d

d[C]/dt=k[A][B]2

answer is A.

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Detailed Solution

On changing the concentration of B to twice without changing the concentration of A, there is no change in the rate of reaction. Hence, the order of the reaction with respect to B is zero. On changing the concentration of A to twice without changing the concentration of B, the rate of reaction becomes twice. Hence, the order of the reaction with respect to A is one.

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