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Q.

Given the data at 25 °C Ag+IAgI+e E=0.152V AgAg++e E=0.800V

What is the value of log Kspfor Agl? (2.303 RT/IF = 0.059 V)

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a

-16.13

b

-8.12

c

+8.612

d

-37.83

answer is A.

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Detailed Solution

E° for the reactionAgIAg++I  is  Ecell 0=(0.8000.152)V=0.952V 

logKsp=EcellRT/F=0.952V0.052V=16.13

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Given the data at 25 °C Ag+I−→AgI+e− E∘=0.152V Ag→Ag++e− E∘=−0.800VWhat is the value of log Ksp∘for Agl? (2.303 RT/IF = 0.059 V)