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Q.

If butanone is treated with $D_{2} O^{18} / DCl$ , isotopic exchange occurs. What is maximum gain in molecular mass is possible in present case.

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answer is 7.

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Detailed Solution

Product formed is

${CH}_{3} {CD}_{2} C \overset{18}{O} {CD}_{3}$

gain in molar mass = 79 -72 =7

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