Q.

In conversion of lime-stone to lime, CaCO3(s)CaO(s)+CO2(g) the value of ΔH and ΔS are +179.1 kJ mol1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ΔH and ΔS

do not change with temperature, temperature above which conversion of lime-stone to lime will be just spontaneous is :

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a

845 K

b

1118 K

c

1008 K

d

1200 K

answer is B.

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Detailed Solution

Here, Gibbs free energy is less than zero.

ΔG<0ΔHTΔS<0T>ΔHΔS=179.1×103160.2=1118K

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