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Questions  

In the reaction p-chlorotoluene with KNH2 in liq. NH3 the major product. is:

a
o-tolutdine
b
m-toluidine
c
p-toluidine
d
p-chloroaniline

detailed solution

Correct option is B

The main result of the reaction between p-chlorotoluene and KNH2 in liquid NH3 is m-Toluidine. The benzyne mechanism drives the reaction.

solution

Hence, the option B is correct. 

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