Q.

 In view of the signs ΔrG of for the following reactions

PbO2+Pb2PbO;    ΔtG<0SnO2+Sn2SnO;    ΔTG>0

Which oxidation states are more characteristic for lead and tin?

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a

For lead +2, for tin +4

b

For lead +4, for tin +4

c

For lead +4, for tin +2

d

For lead +2, for tin +2

answer is D.

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Detailed Solution

ΔrG<0 implies that the reaction is feasible. Thus, the more characteristic oxidation state of lead is +2.

 ΔrG>0 implies that the reaction is not feasible. Thus, the more characteristic oxidation state of tin is +4.

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