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The vapor pressure of a solution at 100°C  containing 3g of cane sugar in 33g of water (vapor pressure of water at 100°C=760mm of Hg) is

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a
756.36 mm of Hg
b
730.36 mm of Hg
c
400 mm of Hg
d
700 mm of Hg

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detailed solution

Correct option is A

Weight of cane sugar w=3g  

Molar mass of cane sugar, M.W=342g/mol

Weight of water (solvent), W=33g

Vapor pressure of pure solvent (water),

P°=760mmofHg

Vapor pressure of solution, P=x

From the Raoult’s law,

P°PP°=wm×MW

760x760=3342×1833

761x=76019×11=3.63

x=7603.63

Vapourpressureofsolution, x=756.36mm of Hg

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