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Q.

The bond angle $H - X - H$ is the greatest in the compound:

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a

$H_{2} O$

b

${PH}_{3}$

c

${CH}_{4}$

d

${NH}_{3}$

answer is B.

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Detailed Solution

${CH}_{4}$ has the greatest $H - C - H$ bond angle. The other molecules have lone pair(s) of electrons. Due to lone pair-bonding pair repulsion, the angle $H - X - H$ is decreased from the expected bond angle of tetrahedral structure. i.e. $109 ° 28' .$

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The bond angle H - X - H is the greatest in the compound: