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Q.

The decreasing order of the rate of the reaction  CH3Br+NuCH3Nu+Brwith nucleophiles NuA to D Nu=(A)PhO, (B) AcOHO (D) CH3O

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a

D>C>A>B

b

D>C>B>A

c

A>B>C>D

d

B>D>C>A

answer is B.

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Detailed Solution

The order acid-strength of the conjugate acids of the given bases is  CH3OH<H2O<PhOH<AcOH The base-strength of the given bases will be

CH3OD>OHC>PhOA>AcOBThe stronger the base, stronger the nucleophile, greater the rate of nucleophilic displacement.

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