The electronic spectrum of [Ti(H₂O)₆]³⁺ shows a single broad peak with a maximum at 20,300cm^–1. The crystal field stabilization energy (CFSE) of the complex ion, in kJmol^–1, is _____ (1kJmol^–1 = 83.7cm^–1)

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answer is 97.

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Detailed Solution

$According to the given information {[Ti {(H_{2} O)}_{6}]^{3 +}}^{}; {Ti}^{3 +} = 3 d^{1} 4 s^{0} CFSE = [0.4 * 1] 20300 = - 8120 {cm}^{- 1} Now, we have the equation : = \frac{- 8120}{83.7} kj / mol = 97 kj / mole$

Hence, correct option is: (A) 97kj/mole

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