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Q.

The equilibrium N2g+O2g2NOg established in a reaction vessel of 2.5 L capacity.

The amount of N2 and O2 taken at the start were respectively 2 moles and 4 moles. Half a mole of nitrogen has been used up at equilibrium. The molar concentration of nitric oxide is

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a

0.2

b

0.4

c

0.6

d

0.1

answer is B.

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Detailed Solution

N2g+O2g2NOg

Initial : 2 4 0

Conc. at equilibrium

        2-X   4-X  2X

According to question on ½ mole ofN2 is used up at equilibrium,

so x=12

n0=2X=21/2=1

Molar concentration =nV=12.5=1025=4.0 mol/lit

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The equilibrium N2g+O2g→2NOg established in a reaction vessel of 2.5 L capacity.The amount of N2 and O2 taken at the start were respectively 2 moles and 4 moles. Half a mole of nitrogen has been used up at equilibrium. The molar concentration of nitric oxide is