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Q.

The equivalent conductivities of two strong electrolytes at infinite dilution in H2O(where ions move freely through a solution) at 25 °C are given below:

ΛCH3COONa=91.0Scm2/ equiv ΛHCl=426.2cm2/ equiv 

What additional information/quantity one needs to calculate of Λof an aqueous solution of acetic acid?

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a

The limiting equivalent conductivity of H+

b

ΛC of NaCl

c

Λ of CH3COOK

d

Λ of chloroacetic acid (CICH2COOH)

answer is A.

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Detailed Solution

We have ΛCH3COOH=ΛCH3COONa+Λ(HCl)Λ(NaCl) Hence, the data of Λ (NaCl)is required.

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