The equivalent conductivities of two strong electrolytes at infinite dilution in H2O(where ions move freely through a solution) at 25 °C are given below:ΛCH3COONa∞=91.0Scm2/ equiv ΛHCl∞=426.2cm2/ equiv What additional information/quantity one needs to calculate of Λ∞of an aqueous solution of acetic acid?

The equivalent conductivities of two strong electrolytes at infinite dilution in H2O(where ions move freely through a solution) at 25 °C are given below:

ΛCH3COONa=91.0Scm2/ equiv ΛHCl=426.2cm2/ equiv 

What additional information/quantity one needs to calculate of Λof an aqueous solution of acetic acid?

  1. A

    ΛC of NaCl

  2. B

    Λ of CH3COOK

  3. C

    The limiting equivalent conductivity of H+

  4. D

    Λ of chloroacetic acid (CICH2COOH)

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    Solution:

    We have ΛCH3COOH=ΛCH3COONa+Λ(HCl)Λ(NaCl) Hence, the data of Λ (NaCl)is required.

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