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The following solid exists in the form of ions

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a
BI3
b
BCl3
c
 BF3
d
CaB2O4

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detailed solution

Correct option is D

Spray pyrolysis was used to build thin films of CaB2O4:Eu on glass substrates. At growth temperatures between 300 and 500°C, the anomalous decrease of Eu3+ to Eu2+ in as-grown thin films was discovered. By annealing films in air, blue cathodoluminescence was discovered, coinciding with additional anomalous Eu ion reduction and compound crystallisation.

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