Q.

The formation of the oxide ion O2(g) requires first an exothermic and then an endothermic step as shown below.

O(g)+e=O(g);    ΔH=142kJmol1O(g)+e=O2(g);    ΔH=844kJmol1

This is because

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a

O ion will tend to resist the addition of another electron

b

O ion has comparatively larger size than oxygen atom.

c

oxygen is more electronegative

d

oxygen has high electron affinity

answer is C.

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Detailed Solution

The addition of negatively-charged electron to the negatively-charged species O requires an input of energy.

O− ion tends to resist the addition of another electron due to large repulsion of e−− e in small sized O− ion. Thus, energy is required to overcome this force of repulsion.

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The formation of the oxide ion O2−(g) requires first an exothermic and then an endothermic step as shown below.O(g)+e−=O−(g);    ΔH∘=−142kJmol−1O−(g)+e−=O2−(g);    ΔH∘=844kJmol−1This is because