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Q.

The indicator constant of an indicator is 104. If pH of solution in which this indicator is present is 3.5, which of the following facts will be correct?

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a

Ionized indicator is present in the larger amount

b

Both ionized and unionized indicator are present in equal amounts

c

Unionized indicator is present in the larger amount

d

Percentage of indicator present in ionized form cannot be predicted

answer is B.

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Detailed Solution

HInH++ + In; Since pH<pKHin, the solution contains larger H+ than that obtained from ionization of  HIn  alone. Hence, the above equilibrium is shift to left, thus more of unionized indicator is present.

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