Q.

The lantharude contraction is responsible for the fact that:

see full answer

Start JEE / NEET / Foundation preparation at rupees 99/day !!

21% of IItians & 23% of AIIMS delhi doctors are from Sri Chaitanya institute !!
An Intiative by Sri Chaitanya

a

Zr and Nb have similar oxidation state.

b

Zr and Hf have almost the same radtus.

c

Zr and Y have almost the same radius.

d

Zr and Zn have the same oxidation state.

answer is C.

(Unlock A.I Detailed Solution for FREE)

Ready to Test Your Skills?

Check your Performance Today with our Free Mock Test used by Toppers!

Take Free Test

Detailed Solution

The size of Zr and Hf is the same because of lanthanide synthesis. The shielding effect can be used to explain lanthanide contraction. The electrons in multi-electron atoms are added to the outer shells. The outer electrons are protected from nuclear charge by the electrons already in the inner shells, resulting in a lower effective charge of the nucleus for them. The inner electrons' shielding effect diminishes in the order of s>p>d>f.

This f subshell does a poor job of protecting the outer electron from nuclear attraction, which leads to a stronger pull from the nucleus and a smaller size. The 4f subshell is filled in the case of post-lanthenide elements like Hf, but it is not particularly efficient at protecting the outer shell. electrons with (n=5 and n=6). Zr is comparable to it.

Watch 3-min video & get full concept clarity

tricks from toppers of Infinity Learn

score_test_img

Get Expert Academic Guidance – Connect with a Counselor Today!

whats app icon