The minimum and maximum values of wavelength in the Lyman series of a H atom are, respectively

The minimum and maximum values of wavelength in the Lyman series of a H atom are, respectively

  1. A

    364.3nm and 653.4 nm

  2. B

    91.2 nm and 121.5 nm

  3. C

    41.2 nm and 102.6 nm

  4. D

    9.12 nm and 121.5 nm

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    Solution:

    For hydrogen like species , use the following formula to calculate the wavelength Of radiation of spectral series lines.

    1λ=R1n12-1n22

    Case 1: Minimum wavelength in the Lyman series:

    n1=1,  n2=2

    Then, 1λ=109677112-122

    1λ=R1-14=3R4

    λ=43R=43×109677cm-1

    λ=1.215×10-5 cm or 121.5nm

    1λ=R1n12-1n22

    Case 2: Maximum wavelength in the Lyman series:

    n1=1   n2=α

    Then, wavelength of line is

    1λ=109677112-1α2

    1λ=1096771-0=109677cm-1

    λ=1109677cm-1=9.117×10-6cm

    λ=91.2nm

    Note:1nm=10-7 cm.

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