The mole fraction of methanol (CH3OH) in aqueous solution is 0.10. If density of the solution is 0.97 g mL-1 , the molarity of the solution will be

The mole fraction of methanol (CH3OH) in aqueous solution is 0.10. If density of the solution is 0.97 g mL-1 , the molarity of the solution will be

  1. A

    4.0 M

  2. B

    4.5 M

  3. C

    5.0 M

  4. D

    5.5 M

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    Solution:

    For x2 = 0.10, let we have n2 = 0.1 mol and n1 = 0.9 mol

    The mass of solution will be

    m=n1M1+n2M2=(0.9mol)18gmol1+(0.1mol)32mol1=19.4g

    The volume of solution will be

    V=mρ=19.4g0.97gmL1=20.0ml=20×103L

    The molarity of solution will be

    M=n2V=0.1mol20×103L=5.0molL1

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