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The molecule having smallest bond angle is

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a

{NCl}_{3}

b

{AsCl}_{3}

c

{SbCl}_{3}

d

{PCl}_{3}

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detailed solution

Correct option is C

The bond angle $Cl - A - Cl$ (where $A$ is $N, P, A$ or $Sb$ ) decreases with the decrease in the electronegativity or increase in the size of the central atom $A$ . Thus, out of ${NCl}_{3},$ ${PCl}_{3}$ , ${AsCl}_{3}$ and ${SbCl}_{3}$ , the latter is expected to have the smallest bond angle.

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