The pH of 0.1 M solution of the following salts increases in the order

The pH of 0.1 M solution of the following salts increases in the order

  1. A

    NaCl<NH4Cl<NaCN<HCl

  2. B

    HCl<NH4Cl<NaCl<NaCN

  3. C

    NaCN<NH4Cl<NaCl<HCl

  4. D

    HCl<NaCl<NaCN<NH4Cl

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    Solution:

    HCl is the strongest acid. Its pH will be minimum. NaCl does not hydrolyse in solution. Its pH= 7 NH4+ in NH4Cl on hydrolysis produces H+. Hence, its pH will be slightly less than 7. CN- in NaCN on hydrolysis produces OH-. Hence, its pH will be slightly greater than 7.

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