Q.

The pH of 0.1MNH4OHKb=1.8×10−5M at 25 °C is

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a

1.8

b

11.13

c

12.2

d

2.87

answer is C.

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Detailed Solution

NH4OH⇌NH4++OH−Keq=NH4+OH−NH4OH≃OH−2NH4OH0 ( since NH4+=OH−)

or OH−=KeqNH4OH0OH−=1.8×10−5×0.1M2OH−=1.34×10−3MpOH=−log⁡OH−/M=2.87; pH=14−pOH=11.13

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