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Q.

The reaction,Ag+2BgCg+Dg is an elementary process . In an experiment, the initial partial pressure of A and B are PA=0.60 and PB=0.80 atm. When PC=0.2 atm the rate of reaction relative to the initial rate is

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a

1/48

b

1/6

c

1/24

d

9/16

answer is D.

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Detailed Solution

A+2BC+D

initial: 0.6  0.8  0  0

after 't' time:0.4   0.4   0.2  0.2

r1=K.PA1×PB2=K×0.6× 0.8× 0.8r2=K×PA1×PB2  after 't' time

r2=K×0.4×0.4×0.4

r2r1=K×0.4×0.4×0.4K×0.6×0.8×0.8=16

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