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Q.

The standard cell potential involving the reaction Cl2(g)+2Br(aq)Br2(l)+2Cl(aq)

ΔrG=50.61 kJ mol1 is

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a

- 0.524 V

b

0.524 V

c

0.262 V

d

-0.262 V

answer is C.

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Detailed Solution

ΔrG=nFEcell ; Ecell =ΔrG/nF;  Ecell =+50.61×103J mol1/(2)(96500 C) =+0.262 V

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The standard cell potential involving the reaction Cl2(g)+2Br−(aq)→Br2(l)+2Cl−(aq)ΔrG∘=−50.61 kJ mol−1 is