Q.

The van't Hoff factor of solutes A, Band C in aqueous solutions are 0.8, 1.6 and 1.2, respectively. The freezing point of equimolar solutions follow the order

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a

 

B>C>A

b

B>A>C

c

A>C>B

d

A>B>C

answer is B.

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Detailed Solution

ΔTf=iΔTf0 For equimolar solutions, large the van't Hoff factor, larger the decrease in freezing point and hence minimum will be the freezing point.

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The van't Hoff factor of solutes A, Band C in aqueous solutions are 0.8, 1.6 and 1.2, respectively. The freezing point of equimolar solutions follow the order