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Which of the following buffer solution will have maximum buffer capacity?

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a
0.1 M acetic acid+ 0.05 M sodium acetate
b
0.05 M acetic acid+ 0.1 M sodium acetate
c
0.05 M acetic acid+ 0.05 M sodium acetate
d
0.1 M acetic acid+ 0.1 M sodium acetate

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detailed solution

Correct option is D

A buffer solution having larger concentrations of acid and conjugate base and also having their ratio equal to one has larger buffer capacity.

buffer capacity is the maximum quantity of acid or base that can be added to a volume of a buffer solution without appreciably changing the pH.

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